Allan C Jacobson

US Patent:

48015709, Jan 31, 1989

Filed:

Jan 29, 1987

Appl. No.:

7/008008

Inventors:

Archie R. Young - Montclair NJ
Teh C. Ho - Bridgewater NJ
Allan J. Jacobson - Princeton NJ
Russell R. Chianelli - Somerville NJ

Assignee:

Exxon Research and Engineering Company - Florham Park NJ

International Classification:

B01J 27047
B01J 27049
B01J 27051

US Classification:

502220

Abstract:

This invention relates to the preparation and use of supported, manganese sulfide promoted molybdenum and tungsten sulfide catalysts useful for hydroprocessing processes, particularly hydrotreating. These catalysts are prepared by heating a composite of support material and precursor salt under oxygen-free conditions and in the presence of sulfur, wherein said precursor salt contains a thiometallate anion of Mo, W or mixture thereof and a cation comprising one or more promoter metals which are chelated by at least one neutral, nitrogen-containing polydentate ligand, and wherein said promoter metal comprises Mn alone or a mixture of Mn with Co, Ni, Zn, Cu or mixture thereof.

US Patent:

43551610, Oct 19, 1982

Filed:

Nov 10, 1980

Appl. No.:

6/205142

Inventors:

Jack W. Johnson - Fanwood NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research and Engineering Co. - Florham Park NJ

International Classification:

C07F 1100

US Classification:

544181

Abstract:

A new composition of matter comprising molybdenum trioxide and heterocyclic nitrogen or oxygen Lewis bases. The molybdenum trioxide, upon reaction with Lewis base, forms a layered compound characterized in that the Lewis base is covalently bonded to molybdenum atoms in molybdenum oxide layers. The layered compound has the formula LMoO. sub. 3 where L is a Lewis base containing nitrogen or oxygen electron donors and selected from the group consisting of 5- and 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides. L has the steric requirement such that its cross-sectional area perpendicular to an axis running through the L-Mo covalent bond is less than about 30(A). sup. 2.

US Patent:

45031665, Mar 5, 1985

Filed:

Apr 16, 1984

Appl. No.:

6/601076

Inventors:

Robert A. Beyerlein - Westfield NJ
Kenneth R. Poeppelmeier - Flemington NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research & Engineering Co. - Florham Park NJ

International Classification:

B01J 2302

US Classification:

502303

Abstract:

A class of cation-reordered, bismuth-containing compounds having a perovskite-type structure of the formula Ba. sub. 2 La. sub. y Bi. sub. 2-y O. sub. 6 wherein y is greater than 0 but less than 1, is provided. Preferably, y is from 0. 25 to 0. 75, and most preferably y is 0. 5. The compositions herein are found to be particularly advantageous in the selective production of aromatic compounds from acyclic olefins, particularly in the production of benzene from propylene.

US Patent:

43551629, Oct 19, 1982

Filed:

Nov 10, 1980

Appl. No.:

6/205141

Inventors:

Jack W. Johnson - Fanwood NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research and Engineering Co. - Florham Park NJ

International Classification:

C07F 1100
C07F 1300

US Classification:

544181

Abstract:

A new composition of matter comprising the reaction product of a mixed oxide having layers of corner linked octahedra and tetrahedra and a Lewis base. The reaction product forms a layered compound of the formula L. sub. x MOM'O. sub. 4 where MOM'O. sub. 4 is a mixed oxide selected from the group consisting of VOPO. sub. 4, VOSO. sub. 4, VOAsO. sub. 4, VOMoO. sub. 4, NbOPO. sub. 4, NbOAsO. sub. 4, TaOPO. sub. 4 and MoOPO. sub. 4, x is from about 0. 1 to 1. 0 and L is a Lewis base containing nitrogen or oxygen electron donor and is selected from the group consisting of 5-membered heterocyclic amines, 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides. The layered compounds are characterized in that L is covalently bound to a metal atom in the MOM'O. sub. 4 layer.

US Patent:

43540244, Oct 12, 1982

Filed:

Nov 10, 1980

Appl. No.:

6/205104

Inventors:

Jack W. Johnson - Fanwood NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research and Engineering Company - Florham Park NJ

International Classification:

C07F 1100

US Classification:

544181

Abstract:

A new composition of matter comprising layered compounds of tungsten trioxide and heterocyclic nitrogen or oxygen Lewis bases which have a unique layered structure. The layered compounds have the formula LWO. sub. 3 where L is a Lewis base selected from the group consisting of 5-membered heterocyclic amines, 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides, the layered compounds being characterized in that L is covalently bound to a tungsten atom in the tungsten oxide layer.

US Patent:

47496738, Jun 7, 1988

Filed:

Aug 18, 1986

Appl. No.:

6/897323

Inventors:

Archie R. Young - Montclair NJ
Teh C. Ho - Bridgewater NJ
Allan J. Jacobson - Princeton NJ
Russell R. Chianelli - Somerville NJ

Assignee:

Exxon Research and Engineering Company - Florham Park NJ

International Classification:

B01J 27051
B01J 27047
B01J 3118

US Classification:

502220

Abstract:

Supported hydroprocessing catalysts comprising a sulfide of trivalent chromium and Mo, W or mixture thereof are obtained by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) a hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising the conjugate acid of at least one neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts derived from cobalt molybdate on alumina.

US Patent:

42372046, Dec 2, 1980

Filed:

Oct 29, 1979

Appl. No.:

6/088828

Inventors:

Arthur H. Thompson - New Providence NJ
Charles R. Symon - Rahway NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research & Engineering Co. - Florham Park NJ

International Classification:

H01M 614

US Classification:

429194

Abstract:

The present invention is directed to an electric current-producing cell which contains: (a) an anode having as its anode-active material one or more metals selected from a group consisting of Periodic Table Group Ia metals, Group Ib metals, Group IIa metals and Group IIb metals; a cathode, comprising: (i) metalized containment means having a plurality of apertures therein, said apertures having an average cross-sectional dimension of about 1 to about 100 microns; and (ii) cathode-active molybdenum sulfide contained within said metalized containment means; and (c) an electrolyte which is chemically inert with respect to said anode and said cathode and which permits the migration of ions between said anode and said cathode.

US Patent:

46221280, Nov 11, 1986

Filed:

Sep 28, 1984

Appl. No.:

6/656146

Inventors:

Archie R. Young - Montclair NJ
Teh C. Ho - Bridgewater NJ
Allan J. Jacobson - Princeton NJ
Russell R. Chianelli - Somerville NJ

Assignee:

Exxon Research and Engineering Company - Florham Park NJ

International Classification:

C10G 7100
C10G 4504

US Classification:

208 18

Abstract:

Supported hydroprocessing catalysts comprising a sulfide of trivalent chromium and Mo, W or mixture thereof are obtained by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) a hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising the conjugate acid of at least one neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts derived from cobalt molybdate on alumina.