Allan J Jacobson

US Patent:

7049259, May 23, 2006

Filed:

Apr 25, 1994

Appl. No.:

08/545707

Inventors:

Harry William Deckman - Clinton NJ, US
Allan Joseph Jacobson - Houston TX, US
James Alexander McHenry - Washington NJ, US
Klaas Keizer - Hoogeveen, NL
Zeger Alexander Eduard Pieter Vroon - Eindhoven, NL
Lothar Ruediger Czarnetzki - Karlsruhe, DE
Frank Wenyih Lai - Bridgewater NJ, US
Antonie Jan Bons - Kessel-Lo, BE
Anthonie Jan Burggraaf - Enschede, NL
Jannetje Maatje van den Berge, legal representative - Oostvoorne, NL
Wilfred Jozef Mortier - Kessel-Lo, BE

Assignee:

ExxonMobil Research and Engineering Company - Annandale NJ

International Classification:

B01J 29/06

US Classification:

502 4, 502 60, 502 64

Abstract:

Layers comprising a molecular sieve layer on a porous or non-porous support, having uniform properties and allowing high flux are prepared from colloidal solutions of zeolite or other molecular sieve precursors (particle size less than 100 nm), by deposition, e. g. , by spin or dip-coating, or by in situ crystallization.

US Patent:

20060189476, Aug 24, 2006

Filed:

Apr 13, 2006

Appl. No.:

11/403683

Inventors:

Harry Deckman - Clinton NJ, US
Allan Jacobson - Houston TX, US
James McHenry - Washington NJ, US
Klaas Keizer - Hoogeveen, NL
Zeger Alexander Vroon - VG Eindhoven, NL
Lothar Czarnetzki - KarIsruhe, DE
Frank Lai - Bridgewater NJ, US
Antonie Bons - Kessel-Lo, BE
Anthonie Burggraaf - AM Enschede, NL
Johannes Verduijn - Leefdaal, BE
Jannetje van den Berge - Oostvoorne, NL
Edward Corcoran - Easton PA, US
Wilfred Mortier - Kessel-Lo, BE

International Classification:

B01J 29/04

US Classification:

502060000

Abstract:

Layers comprising a molecular sieve layer on a porous or non-porous support, having uniform properties and allowing high flux are prepared from colloidal solutions of zeolite or other molecular sieve precursors (particle size less than 100 nm), by deposition, e.g., by spin or dip-coating, or by in situ crystallization.

US Patent:

20060252631, Nov 9, 2006

Filed:

Apr 13, 2006

Appl. No.:

11/403682

Inventors:

Harry Deckman - Clinton NJ, US
Jannetje van den Berge - Oostvoorne, NL
Allan Jacobson - Houston TX, US
James McHenry - Washington NJ, US
Klaas Keizer - Hoogeveen, NL
Zeger Alexander Vroon - Eindhoven, NL
Lothar Czarnetzki - Karlsruhe, DE
Frank Lai - Bridgewater NJ, US
Antonie Bons - Kessel-Lo, BE
Anthonie Burggraaf - Enschede, NL
Johannes Verduijn - Leefdaal, BE
Edward Corcoran - Easton PA, US
Wilfred Mortier - Kessel-Lo, BE

International Classification:

B01J 29/04

US Classification:

502060000

Abstract:

Layers comprising a molecular sieve layer on a porous or non-porous support, having uniform properties and allowing high flux are prepared from colloidal solutions of zeolite or other molecular sieve precursors (particle size less than 100 nm), by deposition, e.g., by spin or dip-coating, or by in situ crystallization.

US Patent:

41443845, Mar 13, 1979

Filed:

Jul 3, 1978

Appl. No.:

5/921256

Inventors:

Allan J. Jacobson - Princeton NJ
Russell R. Chianelli - Somerville NJ
M. Stanley Whittingham - Fanwood NJ

Assignee:

Exxon Research & Engineering Co. - Florham Park NJ

International Classification:

H01M 458

US Classification:

429218

Abstract:

The present invention is directed to an electric current-producing cell which contains: A cathode having as its cathode-active material one or more vanadium compounds selected from: (i) those having the formula: V. sub. a Z. sub. b (1) wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, and sulfur-selenium mixtures, wherein a is a numerical value of about 2, and wherein b is a numerical value of bout 4. 5 to about 7; (ii) those having the formula: (NA. sub. 4). sub. x VZ. sub. y (2) wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, and sulfur-selenium mixtures, wherein x is a numerical value of about 2 to about 4, and wherein y is a numerical value of about 3 to about 5; and, (iii) those having the formula: H. sub. m (NH. sub. 4). sub. n VZ. sub. y (3) wherein Z is a chalcogen selected from the group consisting of sulfur, selenium, and sulfur-selenium mixtures, wherein m is a numerical value of about 1 to about 3 and n is a numerical value of about 1 to about 3, subject to the proviso that the sum of m and n is numerical value of about 2 to about 4, and wherein y is a numerical value of about 3 to about 5. A preferred cathode-electrode material is V. sub. a Z. sub.

US Patent:

45914290, May 27, 1986

Filed:

Sep 28, 1984

Appl. No.:

6/656132

Inventors:

Teh C. Ho - Bridgewater NJ
Archie R. Young - Montclair NJ
Russell R. Chianelli - Somerville NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research and Engineering Co. - Florham Park NJ

International Classification:

C10G 4508
C10G 4904

US Classification:

208254H

Abstract:

Supported, hydroprocessing catalysts comprising a sulfide of (i) trivalent chromium, (ii) Mo, W or mixture thereof and (iii) at least one metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixture thereof with Fe. These catalysts are made by compositing a preselected quantity of support material with a precursor comprising a mixture of (i) hydrated oxide of trivalent chromium and (ii) a salt containing a thiometallate anion of Mo or W and a cation comprising at least one divalent promoter metal chelated by at least one, neutral, nitrogen-containing polydentate ligand and heating the composite in the presence of sulfur and hydrogen in an oxygen-free atmosphere. These catalysts have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as sulfided cobalt-molybdate on alumina.

US Patent:

50264737, Jun 25, 1991

Filed:

May 11, 1990

Appl. No.:

7/521952

Inventors:

Thomas R. Halbert - Annandale NJ
Russell R. Chianelli - Somerville NJ
Edward I. Stiefel - Bridgewater NJ
Allan J. Jacobson - Princeton NJ

Assignee:

Exxon Research & Engineering Company - Florham Park NJ

International Classification:

C10G 4508
C10G 4500

US Classification:

208143

Abstract:

The present invention is based on the discovery that certain transition metal containing complexes thermally decompose to form solids containing the transition metal, sulfur and carbon and that these transition metal, sulfur and carbon containing solids are particularly suitable as catalysts for hydrodesulfurization, hydrodenitrogenation and aromatics hydrogenation. The transition metal complexes that are thermally decomposed to novel catalysts are complexes of the type represented by the general formula ML. sup. n 3, wherein M is selected from Mo, W, Re and mixtures thereof, L is a dithiolene or aminobenzenethiolate ligand, and n represents the total charge of the metal complexes, and is 0, -1, or -2.

US Patent:

47215585, Jan 26, 1988

Filed:

May 30, 1986

Appl. No.:

6/871152

Inventors:

Allan J. Jacobson - Princeton NJ
Teh C. Ho - Bridgewater NJ
Russell R. Chianelli - Somerville NJ
John J. Steger - Pittstown NJ
Angelo A. Montagna - Summit; all of NJ

Assignee:

Exxon Research and Engineering Company - Florham Park NJ

International Classification:

C10G 4508
C10G 4560
C10G 4706

US Classification:

208108

Abstract:

A composition of matter comprising a mixture of (i) a sulfide of at least one promoter metal selected from the group consisting of Ni, Co, Mn, Cu, Zn and mixture thereof and mixtures thereof with Fe, (ii) an amorphous sulfide of trivalent chromium and (iii) microcrystalline of metal sulfide of a metal selected from the group consisting of molybdenum, tungsten and mixture thereof. These compositions have been found to be useful hydrotreating catalysts having nitrogen removal activity superior to that of commercial catalysts such as cobalt-molybdate on alumina.

US Patent:

45930139, Jun 3, 1986

Filed:

Mar 26, 1985

Appl. No.:

6/716040

Inventors:

Allan J. Jacobson - Princeton NJ
Jack W. Johnson - Clinton NJ
Joseph T. Lewandowski - Whitehouse Station NJ

Assignee:

Exxon Research and Engineering Co. - Florham Park NJ

International Classification:

B01J 3102

US Classification:

502167

Abstract:

Disclosed are a class of compositions, and methods of preparing them, which compositions are comprised of inorganic oxides and organic bases. The compositions have layered structures and are represented by the formula Z. sub. a H. sub. b M. sub. c [A. sub. n-1 B. sub. n O. sub. 3n+1 ] where Z is an organic base having a conjugate acid with a pKa value greater than about 3, H is hydrogen, M is a monovalent cation, O