Abstract:
Photothermographic materials have increased photospeed provided by certain organic solvent-soluble thiourea compounds that can be represented by the following Structure I, II, or III: wherein in Structure I, R , R , R and R are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R and R taken together, R and R taken together, R and R taken together or R and R taken together, can form a 5- to 7-membered heterocyclic ring, in Structure II, R , R , R , R and R are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R and R taken together, R and R taken together, R and R taken together or R and R taken together, can form a substituted or unsubstituted 5- to 7-membered heterocyclic ring, and in Structure III, R , R , R , R , R , and R are independently alkyl, cycloalkyl, allyl, alkenyl, alkynyl, aryl or heterocyclic groups, or R and R taken together, R and R taken together, R and R taken together, R and R taken together, or R and R taken together, can form a substituted or unsubstituted 5- to 7-membered heterocyclic ring, and R is a divalent aliphatic or alicyclic linking group. In addition, the speed increasing compounds represented by Structure I do not require a heat activation step at 30Â C. or higher temperature for at least 5 minutes and have a pKa of at least 7.