Metal ions can be removed from aqueous by being brought into contact with a heavy metal removal system which comprises an expanded organophilic clay (such as montmorillonite), a fatty alkyl-containing quaternary ammonium compound (such as a chloride comprising a fatty alkyl group containing from about twelve to about twenty-two carbon atoms), and a fatty alkyl-containing mercaptan (comprising a fatty alkyl group containing from about twelve to about twenty-two carbon atoms).
Preparation Of Rare Earth Alkoxides Using Catalyst
Carl C. Greco - Garnerville NY Johst H. Burk - Mohegan Lake NY
Assignee:
Akzo America Inc. - New York NY
International Classification:
C07F 500
US Classification:
534 15
Abstract:
The reaction of rare earth metals and alcohols, to form rare earth alkoxides, is catalyzed by the use of an inorganic, halide-free mercury salt (e. g. , mercury nitrate or mercury sulfate).
More storage stable solutions comprising an organic solvent containing a soluble copper amino alkoxide are disclosed. The compound is of the formula ##STR1## where and R is lower alkyl such as methyl or ethyl.
Group Vib Metal Carbides From Metal Salicylate Precursors
Carl C. Greco - Garnerville NY Thomas A. Gallo - Thornwood NY Fawzy G. Sherif - Stony Point NY
Assignee:
Akzo N.V. - Arnhem
International Classification:
C01B 3134
US Classification:
423440
Abstract:
Carbides of Group VIB metals, such as tungsten and molybdenum, can be formed by the pyrolysis of a salicylate of such metal. The salicylate can be formed by reaction of a Group VIB metal halide with salicylic acid.
Preparation Of Rare Earth Alkoxides Using Catalyst
Carl C. Greco - Garnerville NY Johst H. Burk - Mohegan Lake NY
Assignee:
Akzo America Inc. - New York NY
International Classification:
C07F 500
US Classification:
534 15
Abstract:
The reaction of rare earth metals and alcohols, to form rare earth alkoxides, is catalyzed by the use of a zinc-containing catalyst, e. g. , zinc and/or zinc chloride.
Carl C. Greco - Garnerville NY Kelly B. Triplett - Stamford CT
Assignee:
Stauffer Chemical Company - Westport CT
International Classification:
C07F 506
US Classification:
556182
Abstract:
There are disclosed improved methods for preparing metal alkoxides from metals and alcohols. The methods involve dry-grinding the metal in an inert atmosphere prior to the addition of the alcohol. When an activator is used, it is usually ballmilled with the metal. Higher yields are obtained, particularly when the metal and alcohol are not very reactive absent an activator. Typical metals are those from Groups 2A, 2B, 3A, and 3B, particularly aluminum, magnesium, and yttrium. Typical alcohols are those which contain up to 16 carbon atoms, particularly those containing 4 or more carbon atoms.
New Method Of Disposing Of The Residue From The Production Of Diaklyl Phosphorochloridothionate
Mark S. Carron - Spring Valley NY Carl C. Greco - Garnerville NY Lester P. VanBrocklin - Thiells NY Francis A. Via - Yorktown Heights NY
Assignee:
Stauffer Chemical Company - Westport CT
International Classification:
C01B 2516
US Classification:
423317
Abstract:
The invention is a method of treating the distillation residue from the production of phosphorochloridothionates which comprises draining the residue into agitated cold water to form a slurry and contacting the slurry with chlorine gas in a hydrolyzing zone to decompose the residue and produce decomposition gases in controllable amounts having a decreased sulfur content. The novel method would reduce the amount of sulfur in the decomposition gas and make possible the use of less costly abatement facilities.
Process For Forming Vanadium Phosphorodithioate Compounds
Vanadium dialkyl phosphorodithioate compounds are formed by the reaction of dialkyl phosphorodithioate acid with a vanadium halide in the presence of a substance capable of removing by-product hydrogen halide from the reaction medium.