Pawan Kumar Agarwal - Houston TX, US Weiqing Weng - Houston TX, US Aspy K. Mehta - Humble TX, US Armenag H. Dekmezian - Kingwood TX, US Main Chang - Houston TX, US Rajan K. Chudgar - League City TX, US Christopher R. Davey - Houston TX, US Chon-Yie Lin - Houston TX, US Galen C. Richeson - Kingwood TX, US Palanisamy Arjunan - Houston TX, US Olivier Jean Georjon - Brussels, BE
Assignee:
ExxonMobil Chemical Patents Inc. - Houston TX
International Classification:
C08F236/20
US Classification:
526339, 526336, 526165
Abstract:
The co-polymerization reaction of one or more olefin monomers, such as propylene, with α,ω-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99. 999 weight percent of olefins and from 0. 001 to 2. 000 weight percent of α,ω-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115 C. to 135 C. and a melt flow rate in the range from 0. 1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1 C. to 8 C.
Polymers Made With Metallocene Catalysts, For Use In Rotomolding And Injection Molding Products
Ethylene alpha-olefin copolymers formed by contacting at least one supported metallocene catalyst, ethylene, and an alpha-olefin in a gas phase reactor are disclosed. In some embodiments, the polymer may have: a density of between 0. 890 and 0. 970 g/cc; a melt index of between 0. 7 and 200 dg/min; a melt index ratio of less than 30; an ESCR value of greater than 1000 hours; and a 1% secant modulus of greater than 75,000 psi. In other embodiments, the polymer may have: a density of between 0. 930 g/cc and 0. 970 g/cc; a melt index of between 10 dg/min and 200 dg/min; a melt index ratio of between 10 and 25; a part weight of greater than 3 g and a part length of greater than 38 cm in a spiral flow test, and; a zero shear viscosity of less than 150 Pas. Processes to produce these polymers are also disclosed.
Polymerization Processes Using Metallocene Catalysts, Their Polymer Products And End Uses
Rainer Kolb - Kingwood TX, US Agapios K. Agapiou - Humble TX, US James M. Farley - League City TX, US Eric J. Markel - Kingwood TX, US Bruce J. Savatsky - Kingwood TX, US Christopher R. Davey - Houston TX, US Richard B. Pannell - Kingwood TX, US
A process for the production of an ethylene alpha-olefin copolymer is disclosed, the process including polymerizing ethylene and at least one alpha-olefin by contacting the ethylene and the at least one alpha-olefin with a metallocene catalyst in at least one gas phase reactor at a reactor pressure of from 0. 7 to 70 bar and a reactor temperature of from 20 C. to 150 C. to form an ethylene alpha-olefin copolymer. The resulting ethylene alpha-olefin copolymer may have a density D of 0. 927 g/cc or less, a melt index (I) of from 0. 1 to 100 dg/min, a MWD of from 1. 5 to 5. The resulting ethylene alpha-olefin copolymer may also have a peak melting temperature Tsatisfying the following relation: T>D*398−245.
Polymerization Processes Using Metallocene Catalysts, Their Polymer Products And End Uses
Rainer Kolb - Kingwood TX, US Agapios K. Agapiou - Humble TX, US James M. Farley - League City TX, US Eric J. Markel - Kingwood TX, US Bruce J. Savatsky - Kingwood TX, US Christopher R. Davey - Houston TX, US Richard B. Pannell - Kingwood TX, US
Assignee:
Univation Technologies, LLC - Houston TX
International Classification:
C08F 4/76 C08F 4/64 C08F 210/02
US Classification:
526328, 525240, 526183, 526348
Abstract:
A process for the production of an ethylene alpha-olefin copolymer is disclosed, the process including polymerizing ethylene and at least one alpha-olefin by contacting the ethylene and the at least one alpha-olefin with a metallocene catalyst in at least one gas phase reactor at a reactor pressure of from 0. 7 to 70 bar and a reactor temperature of from 20 C. to 150 C. to form an ethylene alpha-olefin copolymer. The resulting ethylene alpha-olefin copolymer may have a density D of 0. 927 g/cc or less, a melt index (I) of from 0. 1 to 100 dg/min, a MWD of from 1. 5 to 5. The resulting ethylene alpha-olefin copolymer may also have a peak melting temperature Tsatisfying the following relation: T>D*398−245.
Pawan Agarwal - Houston TX, US Weiqing Weng - Houston TX, US Aspy Mehta - Humble TX, US Armenag Dekmezian - Kingwood TX, US Christopher Davey - Houston TX, US Charlie Lin - Houston TX, US Michael Chen - Houston TX, US Galen Richeson - Kingwood TX, US Rajan Chudgar - League City TX, US Main Chang - Houston TX, US
The co-polymerization reaction of one or more olefin monomers, such as propylene, with ,-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of ,)-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115 C. to 135 C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1 C. to 8 C. More desirably, one of the crystalline populations has a melting point in the range from 152 C. to 158 C. and another crystalline population has a melting point in the range from 142 C. to 148 C.
Pawan Agarwal - Houston TX, US Weiqing Weng - Houston TX, US Aspy Mehta - Humble TX, US Armenag Dekmezian - Kingwood TX, US Christopher Davey - Houston TX, US Charlie Lin - Houston TX, US Michael Chen - Houston TX, US Galen Richeson - Kingwood TX, US
The co-polymerization reaction of one or more olefin monomers, such as propylene, with ,-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of ,-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115 C. to 135 C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1 C. to 8 C. More desirably, one of the crystalline populations has a melting point in the range from 152 C. to 158 C. and another crystalline population has a melting point in the range from 142 C. to 148 C.
Pawan Agarwal - Houston TX, US Weiqing Weng - Houston TX, US Aspy Mehta - Humble TX, US Armenag Dekmezian - Kingwood TX, US Main Chang - Houston TX, US Rajan Chudgar - League City TX, US Christopher Davey - Houston TX, US Charlie Lin - Houston TX, US Michael Chen - Houston TX, US Galen Richeson - Kingwood TX, US
The copolymerization reaction of one or more olefin monomers, such as propylene, with ,-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of ,-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature (without the use of externally added nucleating agents) in the range from 115 C. to 135 C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1 C. to 16 C. More desirably, one of the crystalline populations has a melting point in the range from 152 C. to 158 C. and another crystalline population has a melting point in the range from 142 C. to 148 C.
Pawan Agarwal - Houston TX, US Weiqing Weng - Houston TX, US Aspy Mehta - Humble TX, US Armenag Dekmezian - Kingwood TX, US Main Chang - Houston TX, US Rajan Chudgar - League City TX, US Christopher Davey - Houston TX, US Charlie Lin - Houston TX, US Michael Chen - Houston TX, US Galen Richeson - Kingwood TX, US
International Classification:
C08F236/00 C08F112/34 C08F136/00
US Classification:
526/335000, 526/336000, 526/339000
Abstract:
The co-polymerization reaction of one or more olefin monomers, such as propylene, with ,-diene units and the resulting copolymers are provided. More specifically, the copolymer may have from 90 to 99.999 weight percent of olefins and from 0.001 to 2.000 weight percent of ,-dienes. The copolymer may have a weight average molecular weight in the range from 50,000 to 2,000,000, a crystallization temperature in the range from 115 C. to 135 C. and a melt flow rate in the range from 0.1 dg/min to 100 dg/min. These copolymers may be employed in a wide variety of applications, the articles of which include, for example, films, fibers, such as spunbonded and meltblown fibers, fabrics, such as nonwoven fabrics, and molded articles. The copolymer may further include at least two crystalline populations. Desirably, the melting point range of one of the crystalline populations is distinguishable from the melting point range of another crystalline population by a temperature range of from 1 C. to 8 C. More desirably, one of the crystalline populations has a melting point in the range from 152 C. to 158 C. and another crystalline population has a melting point in the range from 142 C. to 148 C.
incent Kelly, 50, from Lostock, Bolton, and his brother Darren, 45, who moved from Bolton to the village of Isle of Whithorn in southern Galloway a few years ago. Christopher Davey, 51, from Northampton, Stephen Holding, 60, from Stoke-on-Trent, and lawyer Benjamin Ogden, 27, from London also perished.
Date: Sep 29, 2012
Category: World
Source: Google
Witnesses say the twin-engine plane burst into flames before landing near a ...
The other Britons killed were named today by local travel company Sherpa Adventures as Raymond Eagle, 58, Christopher Davey, 51, brothers Vincent Kelly, 50, and Darren Kelly, 45, Timothy Oakes, 57, and Stephen Holding, 60, according to the Press Association.
The British victims were identified by local travel company Sherpa Adventures as Raymond Eagle, 58, Christopher Davey, 51, Vincent Kelly, 50, Darren Kelly, 45, Timothy Oakes, 57, Stephen Holding, 60, and Benjamin Ogden, 27.
The Press Association identified the Britons, quoting local travel company Sherpa Adventures, as Raymond Eagle, 58; Christopher Davey, 51; Vincent Kelly, 50; Darren Kelly, 45; Timothy Oakes, 57; Stephen Holding, 60; and Benjamin Ogden, 27.