John Joseph Rabasco - Allentown PA, US Dennis Sagl - Fogelsville PA, US
Assignee:
Air Products Polymers, L.P. - Allentown PA
International Classification:
C08K005/31
US Classification:
523122, 424 7831, 424 7837, 424405, 524237
Abstract:
This invention is directed to a method of preserving colloid-stabilized polymer emulsions against microbial attack and spoilage using selected cationic compounds. It is also directed to compositions containing colloid-stabilized polymer emulsions and cationic compounds that are resistant to contamination with biodeteriogenic microbes. It has been discovered that specific cationic compounds are particularly effective against biodeteriogenic microbes in preserving polymer emulsions that have been stabilized with protective colloids, such as poly(vinyl alcohol). Examples of suitable microbicidal cationic compounds are: substituted pyridinium salts, substituted guanidine salts, tetrasubstituted ammonium salts, and polymeric cationic compounds.
Method For Increasing The Strength Of A Cellulosic Product
Eric J. Beckman - Aspinwall PA, US W. Eamon Carroll - Orefield PA, US Toby Chapman - Pittsburgh PA, US Kristen E. Minnich - Allentown PA, US Dennis Sagl - Fogelsville PA, US Richard J. Goddard - Fogelsville PA, US
A composition includes at least one hydrophilic polymer containing primary (—NH) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.
Self-Crosslinking Vinyl Acetate-Ethylene Polymeric Binders For Nonwoven Webs
John Joseph Rabasco - Allentown PA, US John Richard Boylan - Bethlehem PA, US Dennis Sagl - Fogelsville PA, US Ronald Bernal Jones - Allentown PA, US
International Classification:
B32B 9/04 B32B 27/12
US Classification:
442155, 442149
Abstract:
This invention is directed to an improvement in nonwoven products comprised of a nonwoven web of fibers bonded together with polymeric binder comprised of emulsion polymerized units of vinyl acetate, ethylene, and a crosslinking monomer. The polymer is stabilized with a surfactant having a critical micelle concentration of about 0. 5 to 3% by weight. The surfactant is employed in the polymerization in an amount less than 1% by weight, based upon the total weight of polymer.
John Joseph Rabasco - Allentown PA, US Dennis Sagl - Fogelsville PA, US
Assignee:
Wacker Chemical Corporation - Adrian MI
International Classification:
C08K 5/34 C08K 5/17 C09D 5/16
US Classification:
523122, 524238, 524239, 524240, 524 99
Abstract:
This invention is directed to a method of preserving polymer emulsions against biodeteriogenic microbe attack and spoilage by combining with the polymer emulsions selected cationic compounds and an ethylenediamine acid compound. The polymer emulsions contain surfactants and/or anionic constituents. It is also directed to polymer emulsion compositions, that are resistant to spoilage by biodeteriogenic microbes, containing surfactants and/or anionic constituents, an ethylenediamine acid compound, and cationic compounds.
Eric J. Beckman - Aspinwall PA, US W. Eamon Carroll - Orefield PA, US Toby Chapman - Pittsburgh PA, US Kristen E. Minnich - Allentown PA, US Dennis Sagl - Fogelsville PA, US Richard J. Goddard - Fogelsville PA, US
Assignee:
University of Pittsburgh—Of the Commonwealth System of Higher Education - Pittsburgh PA
A composition includes at least one hydrophilic polymer containing primary (—NH) and/or secondary (—NHR) amine groups and at least one saccharide containing a reducible function. A method of increasing the strength of paper includes the step of contacting the paper with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function. A hydrogel composition is formed from a mixture of at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function.
N-Vinylamide Polymers As Stabilizing Protective Colloids In Aqueous Emulsion Polymerization
William E. Lenney - Allentown PA Dennis Sagl - Bethlehem PA
Assignee:
Air Products and Chemicals, Inc. - Allentown PA
International Classification:
C08F 230 C08L 3902
US Classification:
524458
Abstract:
A method for preparing aqueous polymer emulsions by effecting polymerization of vinyl monomers in the presence of a stabilizing amount of a water soluble poly(N-vinylformamide) containing polymer as a protective colloid and aqueous polymer emulsions containing poly(N-vinylformamide) stablizer.
Kien Van Phung - Allentown PA Dennis Sagl - Bethlehem PA
Assignee:
Air Products and Chemicals, Inc. - Allentown PA
International Classification:
C08F 1606
US Classification:
525 60
Abstract:
This invention relates to an improved process for producing a vinyl alcohol containing polymer having a narrow particle size without substantial reactor fouling. The process for producing the vinyl alcohol containing polymer involves hydrolyzing a vinyl ester containing polymer, e. g. , a polymer containing polymerized vinyl alkanoate units in the presence of an alcoholic medium and a hydrolysis catalyst in the presence of an alcoholic medium having finely divided, inert material such as an alkali metal carbonate dispersed therein. The finely divided inert material acts as nucleating sites for the polyvinyl alcohol as it precipitates from the solution during hydrolysis.
Dennis Sagl - Macungie PA Menas S. Vratsanos - Breinigsville PA
Assignee:
Air Products and Chemicals, Inc. - Allentown PA
International Classification:
C08L 3306 C08F21808 C08F22012
US Classification:
524559
Abstract:
The present invention relates to a composition for depositing a temporary, selectively soluble protective coating onto a substrate and a process for using the same. The composition consists essentially of a copolymer consisting of 35 to 85 weight percent vinyl acetate and from 15 to 65 weight percent of a predefined monoalkyl maleate which is dispersed in a solvent/vehicle. The protective coatings deposited therefrom are substantially impervious to aqueous media having acidic or neutral pH and provide an effective barrier against damage to the substrate's surface. At the desired time, the protective coating can be removed from the substrate by dissolution in an aqueous alkaline solution.