A process for selectively preparing alpha-olefins having from 2 to about 22 carbon atoms by contacting a gaseous mixture containing carbon monoxide and hydrogen with an iron titanate-alkali metal hydroxide catalyst at reaction conditions correlated so as to favor the formation of a substantial proportion of such alpha-olefin product.
Duane C. Hargis - Southfield MI Lawrence J. Kehoe - Huntington Woods MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
C07C 124
US Classification:
260682
Abstract:
Catalytic process for converting methanol and dimethyl ether to higher hydrocarbons comprising contacting the methanol and/or dimethyl ether with an alumina, silica, or zirconia-supported aluminum sulfate catalyst, at an elevated temperature.
Catalytic Process For The Selective Formation Of Ethanol And Methyl Acetate From Methanol And Synthesis Gas
Duane C. Hargis - Pleasant Ridge MI Michael Dubeck - Birmingham MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
C07C 6736 C07C 6914 C07C 2900 C07C 3108
US Classification:
560232
Abstract:
A process for the selective formation of ethanol and methyl acetate by contacting methanol, hydrogen and carbon monoxide with a catalyst comprising rhodium and iron in the reduced state deposited on a support of alumina containing a minor amount of an alkaline metal at reaction conditions correlated so as to favor the formation of a substantial proportion of ethanol and methyl acetate.
Catalyst For Converting Methanol And Synthesis Gas To Ethanol
Duane C. Hargis - Pleasant Ridge MI Michael Dubeck - Birmingham MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
B01J 3102
US Classification:
252430
Abstract:
A process for selectively preparing ethanol by contacting methanol, hydrogen and carbon monoxide with a solid catalyst comprising rhodium and iron in the reduced state deposited on a support of alumina impregnated with a promoter amount of a heterocyclic amine at reaction conditions correlated so as to favor the formation of a substantial proportion of ethanol.
Process For The Selective Preparation Of Alpha-Olefin From Synthesis Gas
A process for selectively preparing alpha-olefins having from 2 to about 22 carbon atoms by contacting a gaseous mixture containing carbon monoxide and hydrogen with an iron tungstate-alkali metal hydroxide catalyst at reaction conditions correlated so as to favor the formation of a substantial proportion of such alpha-olefin product.
Conversion Of Methanol And Dimethyl Ether To C.sub.2 -C.sub.6 Monoolefins Using A Partially Hydrated Zirconium Sulfate Catalyst
Duane C. Hargis - Southfield MI Lawrence J. Kehoe - Huntington Woods MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
C07C 120
US Classification:
260682
Abstract:
Catalytic process for converting dimethyl ether and methanol to higher hydrocarbons, comprising contacting the dimethyl ether and/or methanol with an alumina, silica or zirconia-supported zirconium sulfate catalyst, at an elevated temperature.
Duane C. Hargis - Pleasant Ridge MI Michael Dubeck - Birmingham MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
C07C 2900
US Classification:
568902
Abstract:
A process for selectively preparing ethanol by contacting methanol, hydrogen and carbon monoxide with a solid catalyst comprising rhodium and iron in the reduced state deposited on a support of alumina impregnated with a promoter amount of a heterocyclic amine at reaction conditions correlated so as to favor the formation of a substantial proportion of ethanol.
Catalytic Composition For The Selective Formation Of Ethanol And Methyl Acetate From Methanol And Synthesis Gas
Duane C. Hargis - Pleasant Ridge MI Michael Dubeck - Birmingham MI
Assignee:
Ethyl Corporation - Richmond VA
International Classification:
B01J 2104 B01J 2358 B01J 2389
US Classification:
252466B
Abstract:
A process for the selective formation of ethanol and methyl acetate by contacting methanol, hydrogen and carbon monoxide with a catalyst comprising rhodium and iron in the reduced state deposited on a support of alumina containing a minor amount of an alkaline metal at reaction conditions correlated so as to favor the formation of a substantial proportion of ethanol and methyl acetate.