Daniel A. Hickman - Midland MI, US James W. Ringer - Midland MI, US
Assignee:
Dow Agrosciences LLC - Indianapolis IN
International Classification:
C07F009/28
US Classification:
562 17
Abstract:
In general the present invention relates to a continuous process for manufacturing (N-phosphonomethyl) glycine, glyphosate, by the catalyzed oxidation of N-phosphonomethyliminodiacetic acid. Glyphosate can be provided in high yield and in a cost efficient process by minimizing the competing side reactions and by-products. The process includes conducting the oxidation reaction and selecting an appropriate catalyst to maximize the rate of the oxidation of N-phosphonomethyliminodiacetic acid while at the same time minimizing the rate of oxidation of glyphosate in the same reaction.
James W. Ringer - Midland MI, US John N. Argyropoulos - Midland MI, US
Assignee:
Dow Global Technologies LLC - Midland MI
International Classification:
C08G 59/60
US Classification:
523400, 523220, 523123, 264261
Abstract:
An epoxy resin reactive diluent composition comprises an epoxy resin diluent (A) and a resin compound (B), wherein the epoxy resin diluent (A) comprises a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety; and wherein the resin compound (B) comprises one or more epoxy resins other than the epoxy resin diluent (A). A curable epoxy resin composition comprises the epoxy resin reactive diluent composition and a curing agent and/or curing catalyst therefore. A cured epoxy resin is prepared by curing the curable epoxy resin composition.
James Ringer - Midland MI, US David Molzahn - Midland MI, US Dennis Hucul - Midland MI, US
International Classification:
C07C051/16
US Classification:
562/538000, 562/523000
Abstract:
Aliphatic primary alcohols, including aliphatic primary alcohols possessing one or more oxygen, nitrogen and/or phosphorus heteroatoms that may be atoms substituting for carbon atoms in the alkyl group or component atoms of substituents on the alkyl group, were converted into salts of carboxylic acids by contacting an alkaline aqueous solution of the primary alcohol with a catalyst comprising cobalt, copper, and at least one of cerium, iron, zinc, and zirconium. Diethanolamine, for example, was converted to sodium iminodiacetate by treatment in an aqueous medium containing sodium hydroxide with a catalyst that was obtained by reducing a mixture of cobalt, copper, and zirconium oxides with hydrogen.
James W. Ringer - Midland MI, US John N. Argyropoulos - Midland MI, US
International Classification:
C08L 63/00 C08G 59/02
US Classification:
523400, 528418, 528408, 525523
Abstract:
Epoxy resins comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety and processes for preparing the epoxy resins. The process of preparation of the epoxy resins comprises reacting (a) a mixture of a cis-1,3-cyclohexanedimethanol, a trans-1,3-cyclohexanedimethanol, a cis-1,4-cyclohexanedimethanol, and a trans-1,4-cyclohexanedimethanol, (b) an epihalohydrin, (c) a basic acting substance, (d) optionally, a solvent, (e) optionally, a catalyst, and/or (f) optionally, a dehydrating agent. The process may be a slurry epoxidation process, an anhydrous epoxidation process, or a Lewis acid catalyzed coupling and epoxidation process.
Adducts Of Epoxy Resins And Process For Preparing The Same
An adduct comprises at least one reaction product of (i) an epoxy resin material (A) and (ii) a reactive compound (B). The epoxy resin material (A) comprises a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety and the reactive compound (B) comprises a compound having two or more reactive hydrogen atoms per molecule, wherein the reactive hydrogen atoms are reactive with epoxide groups. A curable epoxy resin composition comprises the adduct described above. A cured epoxy resin is prepared by a process of curing the curable epoxy resin composition.
Thermoset polyurethanes comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety. Adducts of epoxy resins comprising a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety are used to react with a polyisocyanate to produce the thermoset polyurethanes.
Ronald B. Leng - Midland MI Julie L. Maurer - Midland MI James W. Ringer - Midland MI
Assignee:
Dow AgroSciences LLC - Indianapolis IN
International Classification:
C07D23930 C07D23932 C07D23952
US Classification:
544334
Abstract:
Chloropyrimidine compounds, such as 4,6-dichloro-2-ethoxypyrimidine, were prepared in good yield and good purity from the corresponding hydroxypyrimidine compounds in the absence of organic solvents and with a reduced amount of phosphorus oxychloride by carrying out the reaction in the presence of a trialkylamine compound and phosphorus trichloride. The additions of hydroxypyrimidine compound and trialkylamine compound could be made in segments. The chloropyrimidine compounds produced were recovered in an improved manner by adding chlorine to convert the chlorophosphoric acid by-products and phosphorus trichloride to phosphorus oxychloride, diluting the mixture with additional chloropyrimidine compound and removing the phosphorus oxychloride by distillation, combining the residue with water and a base, distilling the trialkylamine compound from the resulting mixture, and removing the aqueous phase.
Jim Ringer (1969-1977), Tee Forget (1988-1992), Dennis Beckel (1958-1965), Joseph Weisenauer (1973-1980), Denise Gangi (1962-1966), Rosalie Bruno (1980-1988)
Jim Ringer (2009-2010), Jamie Hilty (1997-2001), Hays Mayo (1970-1973), Sharon Wertz (1970-1974), Jim Trovato (1973-1977), Donna Knappenberger (1965-1969)