Hongkun Park - Lexington MA, US Charles M. Lieber - Lexington MA, US Jeffrey J. Urban - Cambridge MA, US Qian Gu - Cambridge MA, US Wan Soo Yun - Somerville MA, US
Assignee:
President and Fellows of Harvard College - Cambridge MA
International Classification:
C30B 29/16
US Classification:
117 68, 117 70, 117 73, 117 74
Abstract:
Nanowires are disclosed which comprise transition metal oxides. The transition metal oxides may include oxides of group II, group III, group IV and lanthanide metals. Also disclosed are methods for making nanowires which comprise injecting decomposition agents into a solution comprising solvents and metallic alkoxide or metallic salt precursors.
Hongkun Park - Lexington MA, US Charles Lieber - Lexington MA, US Jeffrey Urban - Cambridge MA, US Oian Gu - Cambridge MA, US Wan Yun - Daejon, KR
International Classification:
H01L023/58 H01L021/00
US Classification:
438800000, 257798000
Abstract:
Nanowires are disclosed which comprise transition metal oxides. The transition metal oxides may include oxides of group II, group III, group IV and lanthanide metals. Also disclosed are methods for making nanowires which comprise injecting decomposition agents into a solution comprising solvents and metallic alkoxide or metallic salt precursors.
The present invention provides for a composition capable of storing hydrogen from molecular hydrogen. The composition comprises a magnesium nanoparticle (NP) and a polymer, wherein the Mg NC is essentially embedded in the polymer. The polymer is selectively permeable wherein the polymer is essentially not permeable to Oand HO. The composition is capable of absorbing and desorbing molecular hydrogen.
Inorganic Nanostructure-Organic Polymer Heterostructures Useful For Thermoelectric Devices
The Regents of the University of California - Oakland CA, US Jeffrey J. Urban - Emeryville CA, US Rachel A. Segalman - Pleasanton CA, US Nelson E. Coates - Oakland CA, US Shannon K. Yee - Berkeley CA, US
Assignee:
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA - Oakland CA
International Classification:
H01B 1/12
US Classification:
428626, 252500, 428375, 428379, 977755
Abstract:
The present invention provides for an inorganic nanostructure-organic polymer heterostructure, useful as a thermoelectric composite material, comprising (a) an inorganic nanostructure, and (b) an electrically conductive organic polymer disposed on the inorganic nanostructure. Both the inorganic nanostructure and the electrically conductive organic polymer are solution-processable.
Generalized Method For Producing Dual Transport Pathway Membranes
Christine M. Beavers - Pleasant Hill CA, US David K. Britt - El Cerrito CA, US Norman C. Su - Walnut Creek CA, US Daniel T. Sun - Sion, CH Wendy L. Queen - Grimisuat, CH Jeffrey J. Urban - Emeryville CA, US
Assignee:
The Regents of the University of California - Oakland CA
International Classification:
B01D 67/00 B01D 69/14 B01D 53/22
Abstract:
A hybrid polymer/inorganic membrane with dual transport pathways overcomes traditional limitations. The inorganic phase consists of a metal-organic framework (MOF), which is an ideal inorganic dispersant to construct dual transport pathways as the crystalline porous structure of MOFs is more amenable to molecular diffusion than polymers. Previous hybrid membrane research has failed to achieve sufficiently high loadings to establish a percolative network necessary for dual transport, often due to mechanical failure of the membrane at high loading. Using polysulfone and UiO-66-NHMOF as a model system, we achieve high MOF loadings (50 wt %) and observe the evolution from single mode to dual transport regimes. The newly formed percolative pathway through the MOF acts as a molecular highway for gases. As the MOF loading increases to 30 wt %, COpermeability increases linearly from 5.6 barrers in polysulfone homopolymer to 18 barrers. Crucially, between 30 and 40 wt %, a percolative MOF network arises and the COpermeability dramatically rises from 18 to 46 barrers; an eight-fold increase over pure polysulfone, while maintaining selectivity over methane and nitrogen near the pure polymer at 24 and 26, respectively.
Thermoelectric Polymer Aerogels And Methods Of Fabrication Thereof
Edmond W. Zaia - Berkeley CA, US Madeleine P. Gordon - Berkeley CA, US Preston Zhou - Fremont CA, US Boris Russ - Berkeley CA, US Nelson Coates - Oakland CA, US Ayaskanta Sahu - Berkeley CA, US Jeffrey J. Urban - Emeryville CA, US
Assignee:
The Regents of the University of California - Oakland CA
International Classification:
H01L 35/34 C08J 9/26 H01L 35/24
Abstract:
This disclosure provides systems, methods, and apparatus related to thermoelectric polymer aerogels. In one aspect, a method includes depositing a solution on a substrate. The solution comprises a thermoelectric polymer. Solvent of the solution is removed to form a layer of the thermoelectric polymer. The layer is placed in a polar solvent to form a gel comprising the thermoelectric polymer. The gel is cooled to freeze the polar solvent. The gel is placed in a vacuum environment to sublimate the polar solvent from the gel to form an aerogel comprising the thermoelectric polymer.
Ayaskanta Sahu - Berkeley CA, US Boris Russ - Berkeley CA, US Jeffrey J. Urban - Emeryville CA, US Nelson E. Coates - Oakland CA, US Rachel A. Segalman - Santa Barbara CA, US Jason D. Forster - Berkeley CA, US Miao Liu - Richmond CA, US Fan Yang - El Cerrito CA, US Kristin A. Persson - Orinda CA, US Christopher Dames - Berkeley CA, US
Assignee:
The Regents of the University of California - Oakland CA
International Classification:
H01L 21/228 H01L 29/36 H01L 29/06
Abstract:
This disclosure provides systems, methods, and apparatus related to surface doping of nanostructures. In one aspect a plurality of nanostructures is fabricated with a solution-based process using a solvent. The plurality of nanostructures comprises a semiconductor. Each of the plurality of nanostructures has a surface with capping species attached to the surface. The plurality of nanostructures is mixed in the solvent with a dopant compound that includes doping species. During the mixing the capping species on the surfaces of the plurality of nanostructures are replaced by the doping species. Charge carriers are transferred between the doping species and the plurality of nanostructures.
Jeffrey J. Urban - Emeryville CA, US Jared Lynch - Fremont CA, US Nelson Coates - Oakland CA, US Jason Forster - Berkeley CA, US Ayaskanta Sahu - Berkeley CA, US Michael Chabinyc - Santa Barbara CA, US Boris Russ - Berkeley CA, US
Assignee:
The Regents of the University of California - Oakland CA
This disclosure provides systems, methods, and apparatus related to thermoelectric materials. In one aspect, a method includes providing a plurality of nanostructures. The plurality of nanostructures comprise a thermoelectric material, with each nanostructure of the plurality of nanostructures having first ligands disposed on a surface of the nanostructure. The plurality of nanostructures is mixed with a solution containing second ligands and a ligand exchange process occurs in which the first ligands disposed on the plurality of nanostructures are replaced with the second ligands. The plurality of nanostructures is deposited on a substrate to form a layer. The layer is thermally annealed.
Dr. Urban graduated from the University of Minnesota Medical School at Minneapolis in 1991. He works in Marinette, WI and specializes in Pediatrics. Dr. Urban is affiliated with Bellin Hospital.
Robert Douglas, Jason Strylowski, Donald Mckay, Martin Pugliese, James Lenart, Terry Mcguffage, Charles Galvin, Steven Delaney, Tim Williams, Brad Gawlik
Jeff Urban (1976-1980), Nicole Venus (1992-1996), Johnny Robbins (1980-1984), Bill Smith (1967-1971), Andrew Bourn (2001-2005), Doreen Wiesner (1984-1988)
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