Jeremy Barker - Redmond WA M. Yazid Saidi - Redmond WA Jeffrey Swoyer - Bellevue WA
Assignee:
Valence Technology, Inc. - Henderson NV
International Classification:
H01M 458
US Classification:
4292181, 4292311
Abstract:
The invention provides new and novel lithium-metal-fluorophosphates which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-metal-fluorophosphates. The lithium-metal-fluorophosphates comprise lithium and at least one other metal besides lithium.
Jeremy Barker - Redmond WA 98052 Feng Gao - Laurel MD 20733
International Classification:
H01M 1044
US Classification:
320130, 320131
Abstract:
The present invention provides a method for cycling a battery, containing lithium metal oxide, particularly lithium manganese oxide (LMO) active material, in a cell in a manner which reduces the extent to which loss of capacity occurs. The present method of operation extends the cycle life of such battery.
Electrolytes Having Improved Low Temperature Performance
Jeremy Barker - Redmond WA Feng Gao - Henderson NV Arnold Stux - Baltimore MD
Assignee:
Valence Technology, Inc. - Henderson NV
International Classification:
H01M 616
US Classification:
429332
Abstract:
The present invention provides a novel electrolyte solvent which is usable with a variety of carbonaceous and metal oxide electrode active materials, providing improved performance over a broad temperature range, and which is stabilized to maintain cell capacity over a number of cycles.
Lithium Based Phosphates, Method Of Preparation, And Uses Thereof
Jeremy Barker - Redmond WA Steven D. Cochran - Fishers IN
Assignee:
Valence Technology, Inc. - Henderson NV
International Classification:
H01M 1004
US Classification:
429162, 429185, 429249, 205 59, 296232
Abstract:
Conditioning secondary lithium ion cells at elevated temperatures above ambient reduces the time required to complete this process and produces cells and batteries which demonstrate improved electrochemical performance. Conditioning includes subjecting an electrochemical cell to at least one full charge/discharge cycle whereby gases generated and removed before the cell is sealed and ready for use. The cell is placed in an environment that is maintained at a temperature of at least 30Â C. , charged and discharged, and sealed.
In one embodiment, the invention provides a novel composition which is stabilized against decomposition when used as an active material for an electrochemical cell. The active material of the present invention comprises particles of spinel lithium manganese oxide (LMO) enriched with lithium by a decomposition product of lithium hydroxide forming a part of each of the LMO particles. The spinel LMO product formed by the decomposition of lithium hydroxide in the presence of the LMO is characterized by a reduced surface area and increased capacity retention (reduced capacity fading) as compared to the initial, non-treated, non-enriched spinel. In another aspect, the treated spinel LMO product is combined with lithium carbonate in a cathode mixture.
The invention provides novel lithium-mixed metal materials which, upon electrochemical interaction, release lithium ions, and are capable of reversibly cycling lithium ions. The invention provides a rechargeable lithium battery which comprises an electrode formed from the novel lithium-mixed metal materials. Methods for making the novel lithium-mixed metal materials and methods for using such lithium-mixed metal materials in electrochemical cells are also provided. The lithium-mixed metal materials comprise lithium and at least one other metal besides lithium. Preferred materials are lithium-mixed metal phosphates which contain lithium and two other metals besides lithium.
Jeremy Barker - Redmond WA M. Yazid Saidi - Redmond WA
Assignee:
Valence Technology, Inc. - Henderson NV
International Classification:
H01B 108
US Classification:
2525191
Abstract:
A composition and a method for forming the composition stabilized against capacity degradation comprises particles of spinel lithium manganese oxide (LMO) enriched with lithium by a decomposition product of lithium carbonate forming a part of each said particle and characterized by a reduced surface area and increased capacity expressed in milliamp hours per gram as compared to non-enriched spinel.