Ronald Quentin Bennett - Tallmadge OH, US Jeffrey Alan Goodwin - Fairlawn OH, US Jonathan David Rich - Akron OH, US
Assignee:
The Goodyear Tire + Rubber Company - Akron OH
International Classification:
C07C 2/66 C07C 5/22
US Classification:
585323, 585319
Abstract:
This invention relates to a process for synthesizing para-diisopropylbenzene utilizing only cumene and propylene as raw materials. This synthesis technique offers the advantage of eliminating benzene as a raw material used in the process. The elimination of benzene is beneficial because it simplifies the process and eliminates the need to purchase and store benzene for use in the synthesis. The elimination of benzene from the synthesis is of particular value since the use of benzene in industrial applications has been under attack on the basis of environmental, safety, and health concerns. The present invention discloses a process for producing para-diisopropylbenzene from cumene and propylene, said process comprising the steps of (1) introducing a feed stream into an alkylation zone wherein said feed stream is comprised of cumene and propylene, and wherein said alkylation zone contains an alkylation catalyst; (2) allowing the cumene and propylene in the feed stream to react together to produce a first mixture of para-diisopropylbenzene and meta-diisopropylbenzene; (3) fractionally distilling the mixture of para-diisopropylbenzene and meta-diisopropylbenzene in a fractional distillation step to separate the meta-diisopropylbenzene from the para-diisopropylbenzene; (4) isomerizing the meta-diisopropylbenzene in the presence of a transalkylation catalyst to produce a second mixture of para-diisopropylbenzene and meta-diisopropylbenzene; (5) recycling the second mixture of para-diisopropylbenzene and meta-diisopropylbenzene recovered from the transalkylation step to the fractional distillation step; and (6) recovering the para-diisopropylbenzene that was separated from the meta-diisopropylbenzene by the fractional distillation step.
Method For Making Silylaroylhalides And Reaction Products
A method is provided for making silylaroylhalides such as chlorodimethylsilylbenzoyl chloride. Reaction is effected between substantially equivalent amounts of a polyhaloacyl aromatic compound, for example, terephthaloyl chloride and a polyhalopolysilane such as dichlorodisilane in the presence of a palladium catalyst.
Aromatic Polyester-Siloxane Block Copolymers And Method For Making
Peter P. Policastro - Niskayuna NY Pamela K. Hernandez - North Olmsted OH Sandra A. Swint - Schenectady NY Gary C. Davis - Albany NY Jonathan D. Rich - Rexford NY Philip J. McDermott - Clifton Park NY Thomas L. Guggenheim - Scotia NY
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08G 7704
US Classification:
528 26
Abstract:
There is provided by the present invention aromatic polyester-siloxane block copolymers which can be made by effecting the condensation between tetramethyldisiloxane bisbenzoic acid or acid chloride with a dihydric phenol such as bisphenol A or in combination with a mixture of such tetramethyldisiloxane bisbenzoic acid and aromatic acids, such as terephthalic acid or isophthalic acid. The aromatic polyester-siloxane block copolymers can be used as molding compounds, extruded films, in making composite matrix materials and as flame retardants for aromatic polycarbonates.
Peter P. Policastro - Niskayuna NY Pamela K. Hernandez - North Olmsted OH Gary C. Davis - Albany NY Jonathan D. Rich - Rexford NY
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08L 6900
US Classification:
525433
Abstract:
Flame retardant aromatic polycarbonate compositions are provided resulting from the use of certain poly(arylene silicon) materials in combination with aromatic polycarbonates. Included among the poly(arylene silicon) materials are aromatic polyester silioxanes, aromatic polyimide siloxanes and aromatic polysilphenylenes.
Silicone Copolymers Having Tetraorganodisilyloxy Groups And Intermediates Thereof
Jeffrey H. Wengrovius - Scotia NY Virginia M. Van Valkenburgh - Albany NY Jonathan D. Rich - Rexford NY Siegfried H. Schroeter - late of Schenectady NY
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08G 7706
US Classification:
528 21
Abstract:
Silicone copolymers, such as silicone polyimides, silicone polyamides silicone polyesters and silicone polycarbonates are provided having condensed tetraorganodisiloxy groups. These silicone copolymers and anhydride or acylaromatic organic terminated intermediates are crosslinkable by heat or electron beam radiation.
Jonathan D. Rich - Rexford NY Philip J. McDermott - Clifton Park NY Gary C. Davis - Albany NY Peter P. Policastro - Niskayuna NY Karen A. Regh - Clifton Park NY Pamela K. Hernandez - North Olmsted OH Thomas L. Guggenheim - Scotia NY
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08G 7716
US Classification:
528 26
Abstract:
Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.
Daniel J. Brunelle - Scotia NY Thomas L. Guggenheim - Scotia NY James A. Cella - Clifton Park NY Thomas L. Evans - Clifton Park NY Luca P. Fontana - Clifton Park NY Gary R. Faler - Scotia NY James M. Fukuyama - Clifton Park NY Eugene P. Boden - Scotia NY Jonathan D. Rich - Rexford NY Thomas G. Shannon - Evansville IN Sharon J. McCormick - Schenectady NY Philip J. McDermott - Clifton Park NY Alice M. Colley - Latham NY Joseph W. Guiles - Ft Collins CO
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08G 6300 C08G 6942 C07D23100 C07F 704
US Classification:
528352
Abstract:
Macrocyclic oligomers, including polycarbonates, polyesters, polyamides, polyimides, polyetherketones and polyethersulfones, are conveniently prepared from various spiro(bis)indane compounds, especially the 6,6'-difunctional 3,3',3'-tetramethylspiro(bis)indanes. The macrocyclic oligomers may be conveniently converted to linear polymers.
Silicone-Polyamide Block Polymers, Lactam Terminated Organosiloxane And Method For Making
Peter P. Policastro - Schenectady NY Jonathan D. Rich - Ballston Lake NY
Assignee:
General Electric Company - Schenectady NY
International Classification:
C08G 7742
US Classification:
528 26
Abstract:
Silicone-polyamide block polymers are provided which result from the reaction of lactam and silicone having chemically combined arylacyl or arylisocyanato groups. Silicone having terminal aryllactam groups useful for making silicon-polyamide also are provided.
Northwestern Medical GroupBluhm Cardiovascular Institute 675 N Saint Clair St STE 100 FL 19, Chicago, IL 60611 (312)6954965 (phone), (312)6955774 (fax)
Education:
Medical School Albert Einstein College of Medicine at Yeshiva University Graduated: 2004
Procedures:
Cardiac Stress Test Destruction of Benign/Premalignant Skin Lesions Sigmoidoscopy
Conditions:
Hypertension (HTN)
Languages:
English Spanish
Description:
Dr. Rich graduated from the Albert Einstein College of Medicine at Yeshiva University in 2004. He works in Chicago, IL and specializes in Cardiovascular Disease. Dr. Rich is affiliated with Northwestern Lake Forest Hospital and Northwestern Memorial Hospital.
Dr. Rich graduated from the A.T. Still University of Health Sciences/ Kirksville College of Osteopathic Medicine in 1998. He works in Baltimore, MD and specializes in Internal Medicine. Dr. Rich is affiliated with Mercy Medical Center.
Berry Global Oct 2010 - Feb 2018
Chairman and Chief Executive Officer
Algerine Advisors Oct 2010 - Feb 2018
Advisor
Johnson Graduate School of Management at Cornell University Oct 2010 - Feb 2018
Visiting Lecturer
Momentive Jun 2007 - Oct 2010
Chief Executive Officer
The Goodyear Tire & Rubber Company Aug 2000 - Mar 2007
President Chemical and North American Tire
Education:
University of Wisconsin - Madison
Doctorates, Doctor of Philosophy, Philosophy, Organic Chemistry
Iowa State University
Bachelor of Applied Science, Bachelors, Chemistry
Skills:
Board of Directors Executive Management Executive Coaching Teaching Research
Other medical experts in the trial, such as Dr. Jonathan Rich, have said that the restraint and "positional asphyxiation" caused Floyd's oxygen levels to plummet, ultimately resulting in cardiopulmonary arrest.
Prosecutors also called a law enforcement expert and a cardiologist, who both gave testimonies that mirrored those of other expert witnesses. The cardiologist, Dr. Jonathan Rich, said that Mr. Floyds death was absolutely preventable and that he saw no evidence that Mr. Floyd died from a drug over