Kenneth R Light

US Patent:

40899861, May 16, 1978

Filed:

Sep 19, 1977

Appl. No.:

5/834399

Inventors:

Kenneth K. Light - Long Branch NJ
Manfred Hugo Vock - Locust NJ
Edward J. Shuster - Brooklyn NY
Frederick Louis Schmitt - Holmdel NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

A23L 1226

US Classification:

426538

Abstract:

Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 3,3-dimethyl-2(3-butenyl) norbornanol-2 (hereinafter referred to as the "norbornanol derivative" having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof) produced by a process which comprises reacting an allylic Grignard reagent having the structure: wherein X is chloro, bromo or iodo with camphene oxide having the structure: ##STR2## by either "exo" camphene oxide or "endo" camphene oxide or a mixture of "exo" and "endo" camphene oxide. Addition of the said norbornanol derivative to consumable materials is indicated to produce: (a) In foodstuffs, foodstuff flavorings, chewing gums, toothpastes and medicinal products, sweet, fruity, berry-like aromas with woody, incense-like, cedarwood-like, tea-like and floral nuances and incense-like and cedarwood-like flavors with rosey, berry and tea-like nuances; and (b) In perfumes, colognes and perfumed articles, sweet, woody, thujone-like aromas with strong fir-balsam, armoise, cedarleaf, piney, earthy and camphoraceous nuances.

US Patent:

41538110, May 8, 1979

Filed:

Dec 13, 1977

Appl. No.:

5/860142

Inventors:

Kenneth K. Light - Long Branch NJ
James M. Sanders - Eatontown NJ
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY
Joaquin Vinals - Red Bank NJ
William L. Schreiber - Jackson NJ
John B. Hall - Rumson NJ
Denis E. Hruza - Bricktown NJ
Venkatesh Kamath - Red Bank NJ
Braja D. Mookherjee - Holmdel NJ
Ching Y. Tseng - Middletown NJ
Mark A. Sprecker - Sea Bright NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C07C 3302
C07C 3305

US Classification:

568820

Abstract:

Described for use in augmenting or enhancing the organoleptic properties of foodstuffs, chewing gums, toothpastes, medicinal products, tobaccos, perfumes and perfumed articles are one or more hydroxy alkenyl norbornane derivatives having one of the structures: ##STR1##.

US Patent:

40214940, May 3, 1977

Filed:

Aug 11, 1976

Appl. No.:

5/713428

Inventors:

Kenneth K. Light - Long Branch NJ
Edward J. Shuster - Brooklyn NY
Joaquin F. Vinals - Red Bank NJ
Manfred Hugo Vock - Locust NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C07C 4500
C07C 4954

US Classification:

260617F

Abstract:

Described is a process for producing an organic tricyclic alcohol having the formula: ##STR1## wherein each of R. sub. 1, R. sub. 2, R. sub. 3, R. sub. 4, R. sub. 5 and R. sub. 6 is selected from the group consisting of hydrogen and methyl; wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond; and wherein when the dashed line is a carbon-carbon single bond, one of R. sub. 2 or R. sub. 3 is hydrogen.

US Patent:

41488261, Apr 10, 1979

Filed:

Dec 13, 1977

Appl. No.:

5/860140

Inventors:

Kenneth K. Light - Long Branch NJ
James M. Sanders - Eatontown NJ
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY
Joaquin Vinals - Red Bank NJ
William L. Schreiber - Jackson NJ
John B. Hall - Rumson NJ
Denis E. Hruza - Bricktown NJ
Venkatesh Kamath - Red Bank NJ
Braja D. Mookherjee - Holmdel NJ
Ching Y. Tseng - Middletown NJ
Mark A. Sprecker - Sea Bright NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C07C 4500
C07C 4954

US Classification:

260586G

Abstract:

Described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma and perfume aroma augmenting, modifying, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials are one or more alkenyl or alkylidene norbornyl ketone derivatives having the generic structure: ##STR1## wherein R is C. sub. 3 -C. sub. 5 alkenyl or C. sub. 3 -C. sub. 5 alkylidene and the dashed lie is a carbon-carbon single bond or a carbon-carbon double bond, specifically the compounds having the structures: ##STR2## and products produced according to the process of reacting 2-acetyl-3,3-dimethyl-5-norbornene with a complex of N-methylaniline and an alkyl magnesium halide to form a grinard salt of 2-acetyl-3,3-dimethyl-5-norbornene having the structure: ##STR3## said reacting being carried out from -5. degree. C. up to about 40. degree. C. ; reacting the resulting compound with acid aldehyde in the presence of a solvent selected from the group consisting of benzene, tetrahydrofuran, and diethyl ether at a temperature in the range of from -5. degree. C.

US Patent:

42082978, Jun 17, 1980

Filed:

Apr 24, 1979

Appl. No.:

6/032900

Inventors:

Kenneth K. Light - Highlands NJ
James M. Sanders - Eatontown NJ
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY
Joaquin Vinals - Red Bank NJ
William L. Schreiber - Jackson NJ
John B. Hall - Rumson NJ
Denis E. Hruza - Bricktown NJ
Venkatesh Kamath - Red Bank NJ
Braja D. Mookherjee - Holmdel NJ
Ching Y. Tseng - Middletown NJ
Mark A. Sprecker - Sea Bright NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C11D 944
C11D 350

US Classification:

25217411

Abstract:

Described is a process for augmenting or enhancing the aroma of a solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with a solid or liquid cationic, anionic or nonionic detergent base and aroma augmenting or enhancing quantity of at least oxyhydrocarbylnorbornane having the structure: ##STR1## wherein X is carbonyl or carbinyl having the structures, respectively: ##STR2## and wherein at least one of the dashed lines is a carbon-carbon single bond and the other of the dashed lines is a carbon-carbon single bond or a carbon-carbon double bond.

US Patent:

41861493, Jan 29, 1980

Filed:

Feb 2, 1979

Appl. No.:

6/008779

Inventors:

Kenneth K. Light - Long Branch NJ
Bette M. Spencer - Ocean Grove NJ
Joaquin F. Vinals - Red Bank NJ
Jacob Kiwala - Brooklyn NY
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C07C 4500

US Classification:

260586R

Abstract:

Described is a process for preparing cyclohexadiene derivatives having the generic formula: ##STR1## by means of reacting a compound having the structure: ##STR2## with mineral acid selected from the group consisting of dilute hydrochloric acid, dilute phosphoric acid and dilute sulfuric acid; wherein R is C. sub. 1 -C. sub. 5 alkyl. The products produced by this process are useful for their organoleptic properties in perfumes, foodstuffs and tobaccos.

US Patent:

41355202, Jan 23, 1979

Filed:

Dec 13, 1977

Appl. No.:

5/860122

Inventors:

Kenneth K. Light - Long Branch NJ
Bette M. Spencer - Ocean Grove NJ
Joaquin F. Vinals - Red Bank NJ
Jacob Kiwala - Brooklyn NY
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

A24B 312

US Classification:

131 17R

Abstract:

Cyclohexadiene derivatives as tobacco flavoring compositions.

US Patent:

41535685, May 8, 1979

Filed:

Dec 13, 1977

Appl. No.:

5/860144

Inventors:

Kenneth K. Light - Long Branch NJ
James M. Sanders - Eatontown NJ
Manfred H. Vock - Locust NJ
Edward J. Shuster - Brooklyn NY
Joaquin Vinals - Red Bank NJ
William L. Schreiber - Jackson NJ
John B. Hall - Rumson NJ
Denis E. Hruza - Bricktown NJ
Venkatesh Kamath - Red Bank NJ
Braja D. Mookherjee - Holmdel NJ
Ching Y. Tseng - Middletown NJ
Mark A. Sprecker - Sea Bright NJ

Assignee:

International Flavors & Fragrances Inc. - New York NY

International Classification:

C11D 904

US Classification:

252108

Abstract:

Norbornane derivatives are used in soaps. Specifically, mixture of 2-(2-butenoyl)-3,3-dimethylnorbornane; 2-(3-butenoyl)-3,3-dimethylnorbornane and. alpha. -allyl-3,3-dimethyl-2-norbornanemethanol are used.