- Evanston IL, US Liban Jibril - Evanston IL, US Pengcheng Chen - Evanston IL, US
International Classification:
C21D 1/607 B01J 19/00
Abstract:
Disclosed herein are methods for forming one or more nanoparticles. The methods include depositing a solution comprising a block copolymer and a metal salt into one or more square pyramidal nanoholes formed in a substrate, and annealing the substrate to provide a single nanoparticle in each of the one or more square pyramidal nanoholes.
- Evanston IL, US Pengcheng Chen - Evanston IL, US Yuan Liu - Evanston IL, US Jingshan Du - Evanston IL, US
International Classification:
G03F 7/00 C09D 11/102 C08K 5/56 C08G 65/48
Abstract:
A method of preparing a metal nanoparticle can include depositing an ink on a substrate using nanolithography to form a polymer reactor, wherein the ink comprises at least one metalloporphyrin functionalized polymer comprising a metal ion, porphyrin, and a polyethylene oxide polymer; and thermally annealing the polymer nanoreactor under conditions sufficient to form the nanoparticle. The thermal annealing can include a first stage that includes annealing the polymer nanoreactor at a temperature of about 100 C. to about 350 C. for a time sufficient to aggregate the metal ions in the polymer reactor, and a second stage that includes annealing the aggregated polymer nanoreactor at a temperature of about 500 C. to about 600 C. for a time sufficient to reduce the metal ion and decompose a polymer component of the polymer nanoreactor to thereby form the metal nanoparticle.