Compounds having the formula ##STR1## in which R. sub. 1 is alkyl, lower alkenyl, chloro-lower alkyl, lower cycloalkyl, lower alkoxy, thio-lower alkyl, or ##STR2## R. sub. 2 is hydrogen, lower alkoxyalkyl or lower alkanoyl; R. sub. 3 and R. sub. 4 are independently hydrogen, lower alkyl or lower alkoxy; X and Y are independently chloro, fluoro or bromo; Z is hydrogen, methyl, dimethyl, or one methyl and one chloro substituent; and n is 0 or 1. The compounds have utility as herbicides, particularly as post-emergence herbicides.
Method For Preparation Of N-Phosphonomethylglycine
A method for preparing N-phosphonomethylglycine comprising (a) O,O-dialkylaminomethylphosphonate with formaldehyde to produce a triazine; (b) reacting the triazine formed in step (a) with an acyl halide to form the O,O-dialkyl-N-phosphonomethyl-N-chloromethyl acetamide of the acyl halide; (c) reacting the amide formed in step (b) with metal cyanide to form O,O-dialkyl-N-cyanomethyl-N-acetamide; and (d) hydrolyzing the acetamide formed in step (c) to yield N-phosphonomethylglycine.
Processes For The Preparation Of Aryl-.Beta.-Diketones, Arylpyrimidine Ketones And Crop Protection Intermediates
Raymond A. Felix - Richmond CA Hsiao-Ling M. Chin - Moraga CA Frank X. Woolard - Greenbrae CA David L. Lee - Pleasant Hill CA
Assignee:
Zeneca Limited
International Classification:
C07C 4500 C07C 4976 C07C 6500
US Classification:
568314
Abstract:
This invention relates to processes for the preparation of aryl-. beta. -diketones and aryl-pyrimidine ketones. In addition, this invention relates to the preparation of aryl-. beta. -triketones and dimethyl aminomethylene. beta. -diketones, which are useful as crop protection intermediates.
Herbicide antidote compounds having the formula ##STR1## in which R is selected from the group consisting of alkenyl having 2-12 carbon atoms, inclusive; and alkylalkoxy having 1-8 carbon atoms, inclusive.
Raymond A. Felix - Richmond CA Eugene G. Teach - El Cerrito CA
Assignee:
Stauffer Chemical Company - Westport CT
International Classification:
C07D26318 A01N 4300
US Classification:
71 88
Abstract:
A substituted oxazolidone compound having the formula ##STR1## wherein Ar. sup. 1 and Ar. sup. 2 are the same or different and are aromatic or a substituted aromatic group wherein the substituent is selected from chlorine, bromine, chloride or trifluoromethyl, and R is lower alkyl having from 1 to 6 carbon atoms.
An herbicide antidote having the formula: ##STR1## in which X is selected from the group consisting of hydrogen and halogen wherein the halogen is chlorine, bromine or iodine.
Certain 4-Cyclopropylphenyl Geranyl Ethers And Their Use In Controlling Insects
Compounds which are useful for controlling insects by impeding their metamorphosis, have the formula ##STR1## wherein i. A and B together form a bond, II. A and B together form an epoxide link, Or Iii. A is hydrogen and B is C. sub. 1 -C. sub. 4 alkoxy.
Novel biocidal compounds having the general structural formula ##STR1## wherein X is selected from the group consisting of --H, halogen, including --Br, --Cl and --F, C. sub. 1 -C. sub. 4 alkyl, including methyl, ethyl, propyl and butyl.
Jamaica Anesthesia AssocsJamaica Anesthesia Associates PC 8900 Van Wyck Expy FL 1, Richmond Hill, NY 11418 (718)2066088 (phone), (718)2068087 (fax)
Education:
Medical School Univ D'etat D'haiti, Esc De Med Et De Pharmacie, Port Au Prince, Haiti Graduated: 1981
Languages:
Chinese English French Italian Polish Russian Spanish
Description:
Dr. St Felix graduated from the Univ D'etat D'haiti, Esc De Med Et De Pharmacie, Port Au Prince, Haiti in 1981. He works in Richmond Hill, NY and specializes in Anesthesiology.