A method of electrically logging subterranean wells using a conductive fluid includes a miscible combination of an oleaginous fluid, a polar organic solvent, an electrolytic salt, and a carbon dioxide buffer. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like. The electrolytic salt or brine preferably includes a quaternary amine salt having the formula: wherein R is an alkyl having 8 to 18 carbon atoms, Râ is 2 to 6 carbon atoms alkyl group, B is hydrogen, oxyalkyl having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms, A is hydrogen or alkyl with 1 to 4 carbon atoms, x+y=1 to 15, z is 0 to 3, and M is a counter anion; or combinations thereof. The carbon dioxide buffer is preferably a trialkylanol amine.
Arvind D. Patel - Sugar Land TX Reginald Bell - Houston TX Burhan Hoxha - Houston TX Jim Friedheim - Spring TX
Assignee:
M-I LLC - Houston TX
International Classification:
C09K 706
US Classification:
507130, 507243
Abstract:
A fluid having utility in subterranean wells is formulated to include: an oleaginous fluid; and a solids tolerance agent having the formula: in which R is a C to C aliphatic group and Râ is a C to C aliphatic group and x has a value from about 1 to about 10. Preferably Râ is selected from ethyl and isopropyl and R is an unsaturated aliphatic group. The fluid is formulated such that the oleaginous fluid is from about 30% to about 99% by volume of said fluid. In one illustrative embodiment, the oleaginous fluid is composed from about 5% to about 100% by volume of the oleaginous fluid of a material selected from a group consisting of diesel oil, mineral oil, synthetic oil, esters, ethers, acetals, di-alkylcarbonates, olefins, and combinations of these and similar fluids. A non-oleaginous fluid may also be included in the formulation that is from about 1% to about 70% by volume of said fluid. The non-oleaginous fluid is preferably selected from sea water, a brine containing organic or inorganic dissolved salts, a liquid containing water-miscible organic compounds, and combinations thereof.
A method of electrically logging subterranean wells using a conductive double emulsion fluid includes a miscible combination of an oleaginous fluid, an emulsifier capable of forming a microemulsion, an emulsifier capable of forming an invert emulsion, and an electrolytic salt. A microemulsion is the continuous phase of an invert emulsion. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The fluid may additionally contain a polar organic solvent and a carbon dioxide buffer. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like. The electrolytic salt preferably is a quaternary amine salt having the formula: wherein R is an alkyl having 8 to 18 carbon atoms, Râ is 2 to 6 carbon atoms alkyl group, B is hydrogen, oxyalkyl having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms, A is hydrogen or alkyl with 1 to 4 carbon atoms, x+y=1 to 15, z is 0 to 3, and M is a counter anion; or combinations thereof. In such instances the quaternary amine salt serves both as the electrolyte and the microemulsifer.
Biodegradable Surfactant For Invert Emulsion Drilling Fluid
Arvind D. Patel - Sugarland TX Burnhan Hoxha - Houston TX Reginald Bell - Houston TX
Assignee:
M-I LLC - Houston TX
International Classification:
C09K 706
US Classification:
507136, 507138
Abstract:
An invert emulsion drilling fluid includes an oleaginous continuous phase; a non-oleaginous discontinuous phase; a biodegradable surfactant including a di-fatty acid ester of triglycerol; and a weighting agent. It is preferred that the fatty acid have the formula RCO H in which R is an alkyl or alkenyl having 10 to 20 carbon atoms. The oleaginous fluid is selected from diesel oil, mineral oil, synthetic oil, ester oils, glycerides of fatty acids, aliphatic esters, aliphatic ethers, aliphatic acetals, or other such hydrocarbons and combinations of these and similar compounds. The non-oleaginous phase is selected from fresh water, sea water, brine, aqueous solutions containing water soluble organic salts, water soluble alcohols or water soluble glycols or combinations of these and similar compounds. The weighting agent is any suitable weighting agent and is preferably selected from water insoluble weighting agents such as barite, calcite, mullite, gallena, manganese oxides, iron oxides, or combinations of these or water soluble weighting agents such as water soluble salts of zinc, iron, barium, calcium or combinations of these and similar compounds.
Eugene Dakin - Langdon, CA Reginald J. Bell - Sugar Land TX, US Jorge Fernandez - Houston TX, US
Assignee:
M-I L.L.C. - Houston TX
International Classification:
E21B 33/13
US Classification:
166292
Abstract:
A method of converting a completed well into a dual completed well that includes selectively pumping a water-based fluid into a first production zone of the completed well, wherein the water-based fluid has a pH of greater than about 5; allowing the water-based fluid to form a continuous, non-flowing water-based gel in the first production zone of the completed well, wherein the water-based gel has a pH of greater than about 5; disposing a layer of cement into the completed well above the water- based gel; perforating a second production zone of the completed well in a location above the layer of cement; drilling through the layer of cement; and breaking the water-based gel located in the first production zone of the completed well, wherein the breaking comprises: exposing the water-based gel to a breaker fluid, wherein the breaker fluid has a pH of greater than about 5 is disclosed.
ITT Tech -North Houston, TX 2012 to 2016 BS in Project ManagementITT Technical Institute Houston, TX 2011 to 2012 Associate of Applied Science Degree in Computer Drafting and Design
William Frantz Elementary School New Orleans LA 1970-1974, George Washington Elementary School New Orleans LA 1973-1975, Joseph Kohn Junior High School New Orleans LA 1975-1978, GEORGE WASHINGTON CARVER SR. HIGH SC. New Orleans LA 1979-1980
Judith Johnson, Vernon Allen, Harold Perry, David Stamey, Donna Vales, Loretta Sigmon, Charles Biggs, Barbara Burleson, Jack Brown, Rachel Franklin, Forrest Wilson, Joyce Taylor
West Charlotte Senior High Shcool Charlotte NC 1981-1982
Community:
Doug Lewis, Merissa Hannah, Latavia Straite, Lemuel Brown, Ramone Legette, Zoel Murphy, Jennifer Heavner, Dana Hope, Ervin Polk, Jason Beatty, Sarah White