Polyurethane compositions characterized by being heat curable to yield hard, impact-resistant articles having a high heat distortion temperature are disclosed. The cured polyurethane articles are transparent and also hydrolytic and UV light stable as well as being abrasion resistant. The polyurethane is prepared from a cycloaliphatic polyisocyanate, low molecular weight active hydrogen-containing material and optionally a polycarbonate diol. The weight percentage of the urethane moieties and the crosslinked density are carefully controlled so as to provide the proper balance of physical properties, particularly between hardness, flexibility and heat distortion temperature. The polyurethane articles are particularly useful in glazing applications such as aircraft glazing.
Transparent, Optically Clear Poly(Lactone-Urethane) Interlayers For Laminated Safety Glass
Wen-Hsuan Chang - Gibsonia PA Vernon G. Ammons - Glenshaw PA
Assignee:
PPG Industries, Inc. - Pittsburgh PA
International Classification:
C08G 1864 C08G 1865 C08G 1875 B32B 2740
US Classification:
260 775AN
Abstract:
Energy-absorbing interlayers and glass laminates prepared therefrom for use as automobile windshields and other safety glass applications are disclosed. The interlayers are made from a poly(lactone-urethane) in which the molecular weight and structure of the lactone moiety is carefully controlled so as to get optimum energy-absorbing and optical properties.
Energy-absorbing laminates for use as automobile windshields or other safety glass applications comprising a polycarbonate urethane and a sheet of glass are disclosed. The polyurethane is formed from a cycloaliphatic diisocyanate, a compound containing at least two active hydrogens per molecule and having a molecular weight below 250, and a special polycarbonate diol synthesized from a mixture of linear aliphatic and cycloaliphatic diols.
Laminated Articles Prepared From Transparent, Non-Blooming Poly(Lactone-Urethane) Interlayers
Wen-Hsuan Chang - Gibsonia PA Vernon G. Ammons - Glenshaw PA
Assignee:
PPG Industries, Inc. - Pittsburgh PA
International Classification:
C08G 1864 B32B 2740
US Classification:
428412
Abstract:
Energy-absorbing interlayers and glass laminates prepared therefrom for use as automobile windshields and other safety glass applications are disclosed. The interlayers are made from a poly(lactone-urethane) in which the molecular weight and structure of the lactone moiety is carefully controlled so as to get optimum energy-absorbing and optical properties.
Adhesion Control For Safety Glass Laminates Via Polyurethane Composition
Vernon G. Ammons - Glenshaw PA James C. Vanek - New Kensington PA
Assignee:
PPG Industries, Inc. - Pittsburgh PA
International Classification:
C08G 1830 B32B 2718 B32B 2740
US Classification:
260 18TN
Abstract:
An improved polyurethane composition useful as an interlayer for safety glass window applications such as bilayer motor vehicle windshields is disclosed. The polyurethane is specially formulated with an organic silane and an organic phosphorus acid to provide a controlled degree of adhesion to glass maintainable under a wide range Of humidity and temperature conditions, particularly higher temperature and humidity conditions, which are especially detrimental to the maintenance of adhesion. The controlled degree of adhesion between the polyurethane and the glass provides improved penetration resistance in glass-polyurethane safety glass laminates.
Safety Glass Laminates With Aliphatic/Cycloaliphatic Polycarbonate Urethanes
Energy-absorbing laminates for use as automobile windshields or other safety glass applications comprising a polycarbonate urethane and a sheet of glass are disclosed. The polyurethane is formed from a cycloaliphatic diisocyanate, a compound containing at least two active hydrogens per molecule and having a molecular weight below 250, and a special polycarbonate diol synthesized from a mixture of linear aliphatic and cycloaliphatic diols.
Poly(Ether)Urethane Curable At Ambient Temperature Using Butylstannoic Acid Catalyst
A transparent, elastomeric polyurethane which may be cast and cured in place at ambient temperature is prepared by the reaction of a cycloaliphatic diisocyanate with a polyalkylene ether glycol and a crosslinking agent in the presence of butyl stannoic acid catalyst.