Malcolm F. Finlayson - Houston TX Kenneth E. Springs - Clute TX John J. Gathers - Pearland TX James L. Cooper - Lake Jackson TX Walter L. Vaughn - Conroe TX Brian H. Schumann - Clute TX Stephen M. Oliver - Wollerau, CH
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C08L 302
US Classification:
524562, 524734, 427326
Abstract:
Fibrous product is externally sized by applying to the material a basic aqueous dispersion of an interpolymer of an ethylenically unsaturated monomer and an ethylenically unsaturated carboxylic acid comonomer. The preferred dispersions which have lower initial viscosities provide dispersion/starch dilute solutions with higher viscosities and improved external sizing effectiveness. Resulting fibrous products are adequately sized and exhibit excellent printability and strength properties.
Cellulosic Materials Internally Sized With Ammoniated Acid Copolymers And Epihalohydrin/Alkylamine Reaction Products
Walter L. Vaughn - Lake Jackson TX James A. Allen - Clute TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
D21H 340
US Classification:
162164EP
Abstract:
Cellulosic materials such as paper are internally sized by treating fibers of the cellulosic material, e. g. , paper pulp, with a copolymer of an. alpha. ,. beta. -ethylenically unsaturated hydrophobic monomer and an ammoniated. alpha. ,. beta. -ethylenically unsaturated carboxylic acid and a reaction product of epihalohydrin and alkylamine. Internal sizing of the cellulosic material by this method can be carried out over complete range of pH and is not adversely affected by the presence of contaminants such as alum.
Process And Composition For Water- And Oil-Proofing Textiles
An improved process and composition for water- and oil-proofing textiles which comprises treating a textile with a polymeric fluorocarbon finishing agent and at least one reactive polymer extender of the formula ##EQU1## and curing the treated textile at from 80. degree. C to 170. degree. C for 0. 1 to 60 minutes; wherein C. sub. 1 and C. sub. 2 are carbon atoms of a polyalkylene copolymer chain, R and R' are hydrogen, alkyl, phenyl, --COOH or a segment of a polyalkylene chain, R. sub. 1 and R. sub. 2 are alkyl, aryl, aralkyl, alkaryl, or the like, of up to about 20 carbon atoms, and X is a halogen. The treatment in accordance with the present invention results in synergistic improvements in the oil- and/or water-repellent properties of the conventional fluorocarbon agents.
Walter L. Vaughn - Lake Jackson TX Rafael E. Guerra - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B01D 1500 C02F 128
US Classification:
210670
Abstract:
Particles, fibers, or filaments of ethylene/carboxylic acid copolymers or terpolymers, especially in highly porous or microporous form, are employed in removing contaminants from solution in aqueous and/or organic liquids, especially metal contaminants. The porous polymers, having a surface area/weight ratio of at least about 0. 5 m. sup. 2 /gm, are useful alone, but may also be used in conjunction with, or in tandem with, previously known ion exchange resins such as polyacrylic acid crosslinked with divinylbenzene.
Brine Treatment Using Ethylene Carboxylic Acid Polymers
Walter L. Vaughn - Lake Jackson TX Harry S. Burney - Clute TX Robert D. Spradling - Lake Jackson TX Robert R. Frable - Midland MI
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C02F 142
US Classification:
210687
Abstract:
Hardness values (Ca. sup. ++ and Mg. sup. ++) and other polyvalent metal cations are removed from alkali metal brines (esp. NaCl) by using a high surface area ethylene/carboxylic acid polymer (esp. porous ethylene/acrylic acid copolymers).
Process For Producing Porous Fibers From Orientable Olefin Polymers Having Cation-Containing, Pendent Reactive Side-Groups And The Resultant Product
Walter L. Vaughn - Lake Jackson TX Milton S. Wing - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C08J 926 C08J 936 B29B 900 B29C 6720
US Classification:
428364
Abstract:
Novel porous fibers and filaments are prepared from normally solid, thermoplastic, orientable, organic polymers which have reactive or reactable groups pendent from the polymer chain, employing a process which involves reactions of said pendent groups while the polymer is in an oriented condition. One of the preferred polymers is a copolymer of ethylene/acrylic acid.
Walter L. Vaughn - Lake Jackson TX Milton S. Wing - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
B01D 2702 C08K 520 B32B 2734
US Classification:
428224
Abstract:
Novel microporous fibers and filaments are prepared from normally solid, thermoplastic, orientable, organic polymers which have reactive or reactable groups pendent from the polymer chain, employing a process which involves reactions of said pendent groups while the polymer is in an oriented condition. One of the preferred polymers is a copolymer of ethylene/acrylic acid.
Walter L. Vaughn - Lake Jackson TX Milton S. Wing - Lake Jackson TX
Assignee:
The Dow Chemical Company - Midland MI
International Classification:
C07C 9126 C07C 9128
US Classification:
564292
Abstract:
Particles, fibers, or filaments of alkali salts of ethylene/carboxylic acid copolymers or terpolymers, especially in highly porous form, are employed in removing contaminants from tertiary amines or quaternary amine salts, especially metal contaminants.