- Evanston IL, US Qiucheng Li - Evanston IL, US Xiaolong Liu - Ithaca NY, US Eden B Aklile - Evanston IL, US
International Classification:
C01B 32/184 H01L 21/02 H01L 21/285 C01B 35/02
Abstract:
This invention in one aspect relates to a method of synthesizing a self-assembled mixed-dimensional heterostructure including 2D metallic borophene and 1D semiconducting armchair-oriented graphene nanoribbons (aGNRs). The method includes depositing boron on a substrate to grow borophene thereon at a substrate temperature in an ultrahigh vacuum (UHV) chamber; sequentially depositing 4,4″-dibromo-p-terphenyl on the borophene grown substrate at room temperature in the UHV chamber to form a composite structure; and controlling multi-step on-surface coupling reactions of the composite structure to self-assemble a borophene/graphene nanoribbon mixed-dimensional heterostructure. The borophene/aGNR lateral heterointerfaces are structurally and electronically abrupt, thus demonstrating atomically well-defined metal-semiconductor heterojunctions.
Electronically Abrupt Borophene/Organic Lateral Heterostructures And Preparation Thereof
Articles comprising a boron allotrope and an organic compound having a lateral interface one with the other, together with method(s) of preparation of such articles.
Xiaolong Liu (2005-2009), Sarah Taylor (1972-1976), Pepino Thomas (1981-1986), Brad Wilson (1978-1982), Rocky Medina (1998-2001), Jian Zhang (1986-1990)