This invention relates to a multicolor silver halide photographic element comprising a support and at least one high bromide silver halide emulsion layer comprising low fogging tabular silver halide grains, said element further comprising an antifoggant represented by the following Structure I: wherein R is an aliphatic or cyclic group, R and R are independently hydrogen or bromine as long as at least one of them is bromine, L is a divalent linking group, m and n are independently 0 or 1, and SG is a solubilizing group that has a pKa of 8 or less.
Photographic Recording Material For Accelerated Development
John E. Keevert - Rochester NY Stephen P. Singer - Spencerport NY Kenneth J. Reed - Rochester NY Kenneth J. Lushington - Rochester NY Mary C. Brick - Webster NY James A. Friday - Rochester NY
This invention relates to a photographic element comprising a support and at least two silver halide emulsion layers further comprising, an electron transfer agent releasing compound represented by the formula (I): wherein: CAR is a carrier moiety which is capable of releasing â(L) -ETA on reaction with oxidized developing agent; L is a divalent linking group, n is 0, 1 or 2; and ETA is a releasable 1-aryl-3-pyrazolidinone electron transfer agent having a calculated log partition coefficient (c log P) greater than or equal to 2. 40 and the total sum of the Hammett sigma(para) values of the substituents on the 1-aryl ring is 0. 51 or less, the ETA being bonded to L or CAR through either the nitrogen atom in the 2-position or the oxygen attached to the 3-position of the pyrazolidinone ring; and a development accelerator releasing compound represented by the formula (II): wherein: CAR is a carrier moiety which is capable of releasing â(SAM)âNX âNX X on reaction with oxidized developing agent; SAM is a silver absorbable moiety attached to the carrier moiety and is released on reaction with oxidized development agent; and âNX âNX X is a hydrazine group wherein X , X and X are individually hydrogen or a substituent chosen from alkyl, aryl, carbonyl or sulfonyl groups with the proviso that at least one of X , X and X is hydrogen.
Silver Halide Photographic Element Containing Fogged Emulsions For Accelerated Development
Kenneth J. Reed - Rochester NY, US James A. Friday - Rochester NY, US John E. Keevert - Rochester NY, US Stephen P. Singer - Spencerport NY, US Mary C. Brick - Webster NY, US
This invention relates to a negative silver halide photographic element comprising a support and a silver halide imaging layer containing a light sensitive silver halide imaging emulsion, said silver halide imaging layer further comprising a separately precipitated non-imaging intentionally fogged fine grain emulsion and an electron transfer agent releasing compound represented by formula (I):CAR-(L)-ETA (I)wherein:.
Silver Halide Emulsions, Elements And Methods Of Making Same Using Synthetic Biopolymer Peptizers
John E. Keevert - Rochester NY Shane C. Weber - Woodbridge CT Ramesh Jagannathan - Rochester NY Gerald W. Klein - Issaquah WA
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 1015 G03C 1047 C12P 2100
US Classification:
430569
Abstract:
Certain synthetically prepared biopolymers are useful as peptizers in the preparation of photographic silver halide emulsions and elements. Such materials can be used as either nucleation or growth peptizers in place of common peptizing colloids, such as gelatins. The biopolymers can be prepared using recombinant or chemical synthetic methods and designed to have a particular affinity (either high or low) for silver ions. Thus, they can be used to control silver halide grain morphology in the emulsions.
Woodrow G. McDugle - Rochester NY John E. Keevert - Rochester NY Alfred P. Marchetti - Penfield NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 106
US Classification:
430605
Abstract:
Photographic silver halide emulsions are disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing oxo coordination ligands and a transition metal chosen from groups 6, 7, and 8 of the periodic table of elements.
Woodrow G. McDugle - Rochester NY Alfred P. Marchetti - Penfield NY John E. Keevert - Rochester NY Marian S. Henry - Rochester NY Myra T. Olm - Webster NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 108
US Classification:
430567
Abstract:
Photographic silver halide emulsions are disclosed comprised of radiation sensitive silver halide grains exhibiting a face centered cubic crystal lattice structure internally containing a carbonyl coordination ligand and a transition metal chosen from groups 8 and 9 of the periodic table of elements.
John E. Keevert - Rochester NY Woodrow G. McDugle - Rochester NY Raymond S. Eachus - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 106
US Classification:
430567
Abstract:
Photographic silver halide emulsions are disclosed comprised of radiation sensitive silver halide grains containing greater than 50 mole percent chloride and less than 5 mole percent iodide, based on total silver, with any residual halide being bromide, said grains exhibiting a face centered cubic crystal lattice structure formed in the presence of a hexacoordination complex of rhenium, ruthenium, or osmium with at least four cyanide ligands. The emulsions exhibit increased sensitivity.
Preparation Of Thin Tabular Grain Silver Halide Emulsions Using Synthetic Polymeric Peptizers
Wayne A. Bowman - Walworth NY Roger A. Weiss - Webster NY Gerald W. Klein - Issaquah NY John E. Keevert - Rochester NY Shane C. Weber - Rochester NY
Assignee:
Eastman Kodak Company - Rochester NY
International Classification:
G03C 1015 G03C 1005 G03C 104
US Classification:
430569
Abstract:
A process for preparing a thin tabular grain silver halide emulsion comprised of silver halide grains which have a halide content of at least 50 mole percent bromide, wherein tabular grains of less than 0. 15 micrometers in thickness and having an aspect ratio of greater than 8 account for greater than 50 percent of the total grain projected area, comprises the steps of nucleating the silver halide grains with a gelatino-peptizer or with the use of certain synthetic polymers that serve as effective nucleation peptizers and then growing the silver halide grains with the use of either a gelatino-peptizer or certain synthetic polymers that serve as effective growth peptizers.
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